First read this:
http://www.reefkeeping.com/issues/2005-03/rhf/index.phpYou can add vinegar (keep in mind this is a carbon source!), soda water, or closing your windows (increasing CO2).
Your pumps may clog faster, other than that it should not be a problem. 8.6 is a bit high, anything above that could cause major stress on your animals. Generally 7.8-8.5 is acceptable.
Are you dosing limewater or anything in your topoff.
If you are only dosing two-part calc and alk I have a very hard time believing that you pH is running at 8.6.
What are you testing it with?
If you use a meter, try and re-calibrate it. If you use strips, use a meter to measure your pH.