You could do that, however you will have wires between your individual heatsinks.
If this were my tank, this is how I would go about it, referring specifically to the 90 LED kit. I would split the white and blue on separate drivers. I would end up buying a extra driver on top of the kit to bring the total up to 6. They are cheap and don't add much cost, but it leaves you with a lot of added flexibility. That way you can add more LED's to each heatsink in the future if needed, or you can add other colors without having to replace existing LED's. There are more pro's than cons going this route. It also allows you to break them into what I'll call channels, white and blue. I run just the blue Led's to start and end each light cycle.
As far as optics, it all depends how high above the tank your going to run them....65's are a good bet, but with my XP-G Cree's, I'm going to be making the switch to 80's as I feel I'm getting nearly too much light to the bottom of the tank. I don't try to grow SPS on the sand.
As far as heatsinks, I get mine from heatsinkusa.com, I use 10"x10" squares, but that's my personal preference. This again is one of those things that can be done a bunch of different ways.