I don't know if there would be issues with lava rock, I have seen posts about it as a no no over the years but nothing to substantiate it. Hawaii reefs were created from lava rock. Lava rock is basically glass and there certainly is nothing wrong with glass in the tank. There are three types of rock that volcano's make. Scoria, Obsidian & Pumas. Pumas floats so that would be no good but the others I bet are fine. The rock is very sharp so may not be great for fish, there are better options but on a budget I bet it would be fine. Only one way to find out.