What kind of brittlestar is it... Brittlestars in general are considered predators, though most won't actively hunt fish in the tank, and size seems to be a big factor in the fish eating department. Greenbrittle stars have been documented eating fish, once they archieve a larger size... Most may be clumsy at it, some way more proficient; but either way it's a matter of time....
Most have been reported as eating the fish at night, and they usually display unique behaviors which could warrant concern for it's ability to hunt your fish... The will suspend themselves in a fish's sleeping area waiting for the fish to calm down before dropping down on it... they also will sit perched waiting for a fish to swim under them(best way to describe the way they look here is to imagine them making a vertical cage out of their appendages and holding this position for a long duration, or attempting to trap or grab any fish who swims through the cage)...
It is a possibility for a brittlestar to eat a fish, and some unfortunate few have recorded it...