The Day of Week statement is like this.
If DoW SMTWTF- Then OFF .....will turn the outlet off any day, but Saturday
If DoW -M-W-F- Then ON .....will turn the outlet on, Mon, Wed and Friday
Here is an example. This turns the outlet on an hour early on Sat and Sun.
Fallback ON
Set OFF
If Time 07:00 to 08:00 Then ON
If DoW -MTWTF- Then OFF
If Time 08:00 to 19:30 Then ON
Your case is more difficult. We need to use Dummy Outlets, Pretty sure this will work. But I didn't test it.
DUMMY1 (On Saturday from 10 to 18)
Set OFF
If Time 10:00 to 18:00 Then ON
If DoW SMTWTF- Then OFF
DUMMY2 (ON Everyday but Saturday 16 to 22)
Set OFF
If Time 16:00 to 22:00 Then ON
If DoW ------S Then OFF
Light (This is the actual Outlet)
Fallback OFF
Set OFF
If Outlet DUMMY1 = ON Then ON
If Outlet DUMMY2 = ON Then ON
If Temp > 80.0 Then OFF
Min Time 005:00 Then OFF